Thermally induced transformation of a Cu4I4-based cluster to a Cu2I2-based cluster under mild conditions-Reference-Cited by-同舟云学术

Thermally induced transformation of a Cu4I4-based cluster to a Cu2I2-based cluster under mild conditions

Published:2021 Issue:26 Volume:50 Page:9016-9020
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Jiang Cheng-gang¹²³⁴⁵,Yuan Yan-fang¹²³⁴⁵,Meng Xiao-yu¹²³⁴⁵,Zhou Ke-Ke¹²³⁴⁵,Zhuang Gui-lin⁶⁷⁸^ORCID,Li Bao¹²³⁴⁵^ORCID,Zhang Tianle¹²³⁴⁵^ORCID

Affiliation:

1. Key laboratory of Material Chemistry for Energy Conversion and Storage

2. School of Chemistry and Chemical Engineering

3. Huazhong University of Science and Technology

4. Wuhan

5. PR China

6. Institute of Industrial Catalysis

7. College of Chemical Engineering Zhejiang University of Technology

8. People's Republic of China

Abstract

Two isomeric cuprous-iodide complexes from a tetranuclear step-cubane Cu₄I₄ cluster to two butterfly-like Cu₂I₂ units have been synthesized at different temperatures, followed by a clear color change from yellow-orange to deep red.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT01527C

Reference43 articles.

1. Crystal-to-Crystal Transformation between Three CuI Coordination Polymers and Structural Evidence for Luminescence Thermochromism

2. Simultaneous Luminescent Thermochromism, Vapochromism, Solvatochromism, and Mechanochromism in a C3-Symmetric Cubane [Cu4I4P4] Cluster without Cu–Cu Interaction

3. Polymorphic Copper Iodide Clusters: Insights into the Mechanochromic Luminescence Properties

4. Temperature-Dependent 3-D CuI Coordination Polymers of Calix[4]-bis-dithiacrown: Crystal-to-Crystal Transformation and Photoluminescence Change on Coordinated Solvent Removal

5. Manipulating On/Off Single-Molecule Magnet Behavior in a Dy(III)-Based Photochromic Complex

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