Direct synthesis of 2-methylpyridines via I2-triggered [3 + 2 + 1] annulation of aryl methyl ketoxime acetates with triethylamine as the carbon source
Author:
Affiliation:
1. School of Pharmacy
2. Xinxiang Medical University
3. Xinxiang
4. P. R. China
5. Key Laboratory of Pesticide & Chemical Biology
6. Ministry of Education
7. College of Chemistry
8. Central China Normal University
9. Wuhan 430079
Abstract
I2-Triggered reductive generation of iminyl radicals for the synthesis of 2-methylpyridines by employing triethylamine as the carbon source.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/OB/C8OB00349A
Reference41 articles.
1. Profound Methyl Effects in Drug Discovery and a Call for New CH Methylation Reactions
2. Metal-Free Multicomponent Syntheses of Pyridines
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