Elemental chalcogen reactions of a tetravalent uranium imidophosphorane complex: cleavage of dioxygen-Reference-Cited by-同舟云学术

Elemental chalcogen reactions of a tetravalent uranium imidophosphorane complex: cleavage of dioxygen

Published:2022 Issue:95 Volume:58 Page:13242-13245
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Aguirre Quintana Luis M.¹^ORCID,Rajeshkumar Thayalan²,Jiang Ningxin¹^ORCID,Niklas Julie E.¹,Bacsa John¹,Maron Laurent²^ORCID,La Pierre Henry S.¹³^ORCID

Affiliation:

1. School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332-0400, USA

2. Laboratoire de Physique et Chimie des Nano-objets, Institut National des Sciences Appliquees, 31077 Toulouse, Cedex 4, France

3. Nuclear and Radiological Engineering and Medical Physics Program, School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332-0400, USA

Abstract

The activation and atom-transfer reactions between a homoleptic U(iv) imidophosphorane complex and O2, S8, and Se0 are reported.

Funder

Consejo Nacional de Ciencia y Tecnología

U.S. Department of Energy

Georgia Institute of Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC05066H

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2. Uranium-mediated activation of small molecules

3. Towards uranium catalysts

4. Metallacyclic actinide catalysts for dinitrogen conversion to ammonia and secondary amines

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