First principles studies on the selectivity of dimethoxymethane and methyl formate in methanol oxidation over V2O5/TiO2-based catalysts
Author:
Affiliation:
1. CAS Key Laboratory of Low-Carbon Conversion Science and Engineering
2. Shanghai Advanced Research Institue
3. Chinese Academy of Sciences
4. Shanghai 201210
5. China
Abstract
An intermediate formed from methanol chemisorption plays a key role in the formation of formaldehyde, methyl formate, and dimethoxymethane.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP02326J
Reference57 articles.
1. One-pot 1,1-dimethoxymethane synthesis from methanol: a promising pathway over bifunctional catalysts
2. Methanol Selective Oxidation to Formaldehyde over Iron‐Molybdate Catalysts
3. Selective One-Step Synthesis of Dimethoxymethane via Methanol or Dimethyl Ether Oxidation on H3+nVnMo12-nPO40 Keggin Structures
4. A novel strategy for conversion of methanol and CO2 into dimethoxymethane in a basic ionic liquid
5. Selective Oxidation of Methanol and Ethanol on Supported Ruthenium Oxide Clusters at Low Temperatures
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