A molecular electron density theory study on the [3+2] cycloaddition reaction of thiocarbonyl ylides with hetaryl thioketones-Reference-Cited by-同舟云学术

A molecular electron density theory study on the [3+2] cycloaddition reaction of thiocarbonyl ylides with hetaryl thioketones

Published:2018 Issue:14 Volume:42 Page:11819-11830
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Asr Afsaneh¹²³⁴⁵,Aghaie Mehran¹²³⁴⁵,Emamian Saeedreza⁶⁷³⁸⁵^ORCID,Aghaie Hossein⁶⁹³⁴⁵

Affiliation:

1. Faculty of Chemistry

2. North-Tehran Branch

3. Islamic Azad University

4. Tehran

5. Iran

6. Chemistry Department

7. Shahrood Branch

8. Shahrood

9. Science and Research Branch

Abstract

In situ generated TCY 2 is trapped with THK 3 over the course of a non-polar, entirely C1–C4 regioselective, pdr-type 32CA reaction passing through TS 1 in a non-concerted two-stage one-step molecular mechanism.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C8NJ02021C

Reference61 articles.

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3. [3+2] cycloaddition reaction between CF3-substituted thiocarbonyl ylides and thioketones: Exploration of regioselectivity and mechanistic aspects using Molecular Electron Density Theory

4. Asymmetric 1,3-Dipolar Cycloaddition Reactions

5. Understanding the mechanisms of [3+2] cycloaddition reactions. The pseudoradical versus the zwitterionic mechanism

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