Synthesis and characterization of heteroleptic rare earth double-decker complexes involving tetradiazepinoporphyrazine and phthalocyanine macrocycles

Author:

Tarakanova Ekaterina N.12345ORCID,Tarakanov Pavel A.56789ORCID,Simakov Anton O.5678,Furuyama Taniyuki10111213ORCID,Kobayashi Nagao14151613ORCID,Konev Dmitry V.967817,Goncharova Olga A.9678,Trashin Stanislav A.567818,De Wael Karolien1819202122ORCID,Sulimenkov Ilya V.23678,Filatov Vasily V.23678,Kozlovskiy Viatcheslav I.23678,Tomilova Larisa G.567819,Stuzhin Pavel A.1234ORCID,Pushkarev Victor E.5678ORCID

Affiliation:

1. Research Institute of Macroheterocycles

2. Ivanovo State University of Chemistry and Technology

3. RF-153000 Ivanovo

4. Russia

5. Institute of Physiologically Active Compounds

6. Russian Academy of Sciences

7. Chernogolovka 142432

8. Russian Federation

9. Institute of Problems of Chemical Physics

10. Graduate School of Natural Science and Technology

11. Kanazawa University

12. Kakuma-machi

13. Japan

14. Faculty of Textile Science and Technology

15. Shinshu University

16. Tokida

17. D. I. Mendeleev University of Chemical Technology of Russia

18. AXES Research Group

19. Department of Chemistry

20. University of Antwerp

21. 2020 Antwerpen

22. Belgium

23. Chernogolovka Branch of the N.N. Semenov Federal Research Center for Chemical Physics

Abstract

We report novel heteroleptic lanthanide sandwich complexes (Ln = Lu, Eu, La) and their spectral, electrochemical and computational studies.

Funder

Russian Foundation for Basic Research

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference58 articles.

1. H. S. Nalwa , Supramolecular Photosensitive and Electroactive Materials , Elsevier Science , 2001

2. Single-molecule magnetism of tetrapyrrole lanthanide compounds with sandwich multiple-decker structures

3. Y. Bian , Y.Zhang , Z.Ou and J.Jiang , in Handbook of Porphyrin Science , World Scientific Publishing Company , 2011 , vol. 14 , pp. 249–460

4. Lanthanide macrocyclic complexes: from molecules to materials and from materials to devices

5. G. Aromí and O.Roubeau , in Including Actinides , ed. and J.-C. G. Bünzli and V. K. B. T.-H. on the P. and C. of R. E. Pecharsky , Elsevier , 2019 , vol. 56 , pp. 1–54

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