Synthesis, characterization, and high-pressure studies of a 3D berkelium(iii) carboxylate framework material

Author:

Sperling Joseph M.1ORCID,Beck Nicholas1ORCID,Scheibe Benjamin1ORCID,Bai Zhuanling1ORCID,Brannon Jacob1ORCID,Gomez-Martinez Daniela1ORCID,Grödler Dennis2ORCID,Johnson Jason A.3ORCID,Lin Xinsong1,Rotermund Brian M.1ORCID,Albrecht-Schönzart Thomas E.1

Affiliation:

1. Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, RM. 118 DLC, Tallahassee, Florida 32306, USA

2. Department of Chemistry, Institute for Inorganic Chemistry, University of Cologne, Greinstr. 4-6, 50939 Cologne, Germany

3. Environmental Health and Safety, Florida State University, Tallahassee, Florida 32310, USA

Abstract

A berkelium mellitate is added to a small family of structurally characterized Bk compounds. The 5f → 5f transitions on average blue shift and the compound changes colour with applied pressure unlike other actinide mellitates.

Funder

U.S. Department of Energy

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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