Controlled keto–enol tautomerism of coumarin containing β-ketodithioester by its encapsulation in cucurbit[7]uril
Author:
Affiliation:
1. Pontificia Universidad Católica de Chile
2. Facultad de Química
3. Santiago
4. Chile
5. Universidad de Santiago de Compostela
6. Departamento de Quimica Fisica
7. Facultad de Quimica
8. Spain
Abstract
CB7 shifts the tautomeric equilibrium of CAM2, from the enol- to keto-form, whereas β-CD maintains the enol form.
Funder
Fondo Nacional de Desarrollo Científico y Tecnológico
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C7NJ03265J
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3. The Structural Basis of Ribosome Activity in Peptide Bond Synthesis
4. Spectral−Structural Effects of the Keto−Enol−Enolate and Phenol−Phenolate Equilibria of Oxyluciferin
5. Temperature-Induced Reversal of Proton Tautomerism: Role of Hydrogen Bonding and Aggregation in 7-Hydroxyquinolines
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