CaCl2 molten salt hydrate-promoted conversion of carbohydrates to 5-hydroxymethylfurfural: an experimental and theoretical study-Reference-Cited by-同舟云学术

CaCl2 molten salt hydrate-promoted conversion of carbohydrates to 5-hydroxymethylfurfural: an experimental and theoretical study

Published:2021 Issue:5 Volume:23 Page:2058-2068
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Lin Changqu¹²³⁴,Chai Chaoqun⁵⁶²³⁴,Li Yuanzhang¹²³⁴,Chen Jiao¹²³⁴,Lu Yanyu¹²³⁴,Wu Hongli¹²³⁴,Zhao Lili⁵⁶²³⁴^ORCID,Cao Fei¹²³⁴^ORCID,Chen Kequan¹²³⁴^ORCID,Wei Ping¹²³⁴,Ouyang Pingkai¹²³⁴

Affiliation:

1. College of Biotechnology and Pharmaceutical Engineering

2. Nanjing Tech University

3. Nanjing

4. P. R. China

5. Institute of Advanced Synthesis

6. School of Chemistry and Molecular Engineering

Abstract

33.6% fructose and 52.1% HMF were achieved from glucose isomerization and dehydration in CaCl₂ salt hydrate. Interactions existing in β-glucopyranose-CaCl₂ and β-d-fructofuranose-Ca²⁺ promoted the glucose isomerization and fructose dehydration.

Funder

National Key Research and Development Program of China

Jiangsu National Synergistic Innovation Center for Advanced Materials

National Natural Science Foundation of China

Six Talent Peaks Project in Jiangsu Province

Nanjing Tech University

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/GC/D0GC04356G