Copper-catalyzed non-directed hydrosilylation of cyclopropenes: highly diastereoselective synthesis of fully substituted cyclopropylsilanes

Author:

Wang Hui12345,Zhang Ge12345,Zhang Qian12345,Wang Ying12345,Li Yanfei12345,Xiong Tao12345ORCID,Zhang Qian12345

Affiliation:

1. Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis

2. Department of Chemistry

3. Northeast Normal University

4. Changchun 130024

5. China

Abstract

The non-directed hydrosilylation of cyclopropenes with earth-abundant and environmentally benign base metal catalysis was described.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference81 articles.

1. B. Marciniec , Hydrosilylation, A Comprehensive Review on Recent Advances , Spring , 2009

2. I. Ojima , S.Patai and Z.Rappoport , The Chemistry of Organic Silicon Compounds , Wiley Interscience , New York , 1989 , pp. 1479–1526

3. M. A. Brook , Silicon in Organic, Organometallic, and Polymer Chemistry , Wiley , 2000

4. A New Hydrosilylation Mechanism—New Preparative Opportunities

5. Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view

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