Competition between hydrogen bonds and van der Waals forces in intermolecular structure formation of protonated branched-chain alcohol clusters

Author:

Sugawara Natsuko12345,Hsu Po-Jen6789ORCID,Fujii Asuka12345ORCID,Kuo Jer-Lai6789ORCID

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Tohoku University

4. Sendai 980-8578

5. Japan

6. Institute of Atomic and Molecular Sciences

7. Academia Sinica

8. Taipei 10617

9. Taiwan

Abstract

Temperature dependence of hydrogen bond network structures of protonated bulky alcohol clusters is explored by IR spectroscopy and DFT simulations.

Funder

Japan Society for the Promotion of Science

Ministry of Science and Technology, Taiwan

Academia Sinica

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference72 articles.

1. G. A. Jeffrey , An Introduction to Hydrogen Bonding , Oxford University Press , Oxford , 1997

2. A. J. Stone , The Theory of Intermolecular Forces , Clarendon Press , Oxford , 1996

3. Patterns in Hydrogen Bonding: Functionality and Graph Set Analysis in Crystals

4. Structure and vibrational spectra of methanol clusters from a new potential model

5. Infrared Spectroscopy of Size-Selected Water and Methanol Clusters

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