Selective reduction of 1,5-diazacyclooctatetraenes: synthesis and structures of aromatic diazacyclooctatetraenyl dianions and a 2,6-bipyrrolinyl dianionic Co(ii) complex-Reference-Cited by-同舟云学术

Selective reduction of 1,5-diazacyclooctatetraenes: synthesis and structures of aromatic diazacyclooctatetraenyl dianions and a 2,6-bipyrrolinyl dianionic Co(ii) complex

Published:2019 Issue:18 Volume:55 Page:2648-2651
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Huang Zhe¹²³⁴⁵,Tan Gengwen⁶⁷⁸⁹¹⁰,Chen Chao⁶⁷⁸⁹¹⁰,Zhang Wen-Xiong¹²³⁴⁵^ORCID,Wang Xinping⁶⁷⁸⁹¹⁰^ORCID,Xi Zhenfeng¹²³⁴⁵^ORCID

Affiliation:

1. Beijing National Laboratory for Molecular Sciences (BNLMS)

2. Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education

3. College of Chemistry

4. Peking University

5. Beijing 100871

6. State Key Laboratory of Coordination Chemistry

7. School of Chemistry and Chemical Engineering

8. Nanjing University

9. Nanjing 210023

10. China

Abstract

The first structurally well-defined aromatic 1,5-diazacyclooctatetraenyl dianion and a 2,6-bipyrrolinyl dianionic Co(ii) complex were obtained selectively via reduction of 1,5-diazacyclooctatetraenes.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC00075E

Reference42 articles.

1. THE CYCLOÖCTATETRAENYL DIANION

2. THE CHEMICAL INTERACTION OF THE CYCLO-OCTATETRAENYL ANIONS

3. Dipotassium(I) cyclooctatetraenide–1-methoxy-2-(2-methoxyethoxy)ethane

4. Structure of the 10.pi. electron cyclooctatetraene dianion in potassium diglyme 1,3,5,7-tetramethylcyclooctatetraene dianion, [K((CH3OCH2CH2)2O)]2[C8H4(CH3)4]

5. Crystal structure of cyclooctatetraenylpotassium, C8H8K2·(OC4H8)3

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