On the reaction mechanism of redox transmetallation of elemental Yb with Hg(C6F5)2 and subsequent reactivity of Yb(C6F5)2 with pyrazole: a DFT investigation-Reference-Cited by-同舟云学术

On the reaction mechanism of redox transmetallation of elemental Yb with Hg(C6F5)2 and subsequent reactivity of Yb(C6F5)2 with pyrazole: a DFT investigation

Published:2015 Issue:82 Volume:51 Page:15173-15175
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Lefèvre Julia¹²³⁴⁵,Deacon Glen B.⁶⁷⁸⁹,Junk Peter C.¹⁰¹¹¹²¹³⁹,Maron Laurent¹²³⁴⁵

Affiliation:

1. Université de Toulouse et CNRS INSA

2. UPS

3. CNRS

4. UMR 5215

5. LPCNO

6. School of Chemistry

7. Monash University

8. Clayton Vic 3800

9. Australia

10. College of Science

11. Technology & Engineering

12. James Cook University

13. Townsville

Abstract

DFT investigations of the redox transmetallation reaction of the diorganomercurial (Hg(C₆F₅)₂) with Yb metal, yielding Yb(C₆F₅)₂, allowed us to define a very low energy reaction mechanism via a C₆F₅Yb–HgC₆F₅ intermediate.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC05439G

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