4,4′-Di-tert-butyl-6-(1H-tetrazol-5-yl)-2,2′-bipyridine: modification of a highly selective N-donor ligand for the separation of trivalent actinides from lanthanides-Reference-Cited by-同舟云学术

4,4′-Di-tert-butyl-6-(1H-tetrazol-5-yl)-2,2′-bipyridine: modification of a highly selective N-donor ligand for the separation of trivalent actinides from lanthanides

Published:2017 Issue:30 Volume:46 Page:9981-9994
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Maiwald Martin M.¹²³⁴⁵^ORCID,Wagner Anna T.⁶⁷⁸⁴,Kratsch Jochen⁶⁷⁸⁴,Skerencak-Frech Andrej¹²³⁴⁵,Trumm Michael⁵⁷⁹⁴,Geist Andreas⁵⁷⁹⁴,Roesky Peter W.⁶⁷⁸⁴^ORCID,Panak Petra J.¹²³⁴⁵

Affiliation:

1. Physikalisch-Chemisches Institut

2. Ruprecht-Karls-Universität Heidelberg

3. 69120 Heidelberg

4. Germany

5. Institut für Nukleare Entsorgung (INE)

6. Institut für Anorganische Chemie

7. Karlsruher Institut für Technologie (KIT)

8. 76131 Karlsruhe

9. 76021 Karlsruhe

Abstract

In the present work, the complexation and extraction behaviour of HN₄^tbubipy towards An(iii) and Ln(iii) is studied by spectroscopy, solvent extraction, and QM calculations.

Funder

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01864A

Reference72 articles.

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3. R. Taylor , Reprocessing and Recycling of Spent Nuclear Fuel, Woodhead Publishing, 2015

4. Assessment of the environmental footprint of nuclear energy systems. Comparison between closed and open fuel cycles

5. An overview and historical look back at the solvent extraction using nitrogen donor ligands to extract and separate An(III) from Ln(III)

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