Yb(NTf2)3/HFIP induced high isotacticity in atom transfer radical polymerization of methyl methacrylate-Reference-Cited by-同舟云学术

Yb(NTf2)3/HFIP induced high isotacticity in atom transfer radical polymerization of methyl methacrylate

Published:2018 Issue:38 Volume:9 Page:4711-4715
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Schaubach Sebastian¹²³⁴⁵,Wang Xiao-Yan¹²³⁴⁵^ORCID,Li Jun-Fang¹²³⁴⁵,Sun Xiu-Li¹²³⁴⁵,Wang Sunewang R.¹²³⁴⁵,Tang Yong¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Organometallic Chemistry

2. Shanghai Institute of Organic Chemistry

3. Chinese Academy of Sciences

4. Shanghai 200032

5. China

Abstract

Highly efficient Lewis acid Yb(NTf₂)₃ (1–8 mol%) for a high triad isotacticity (up to 69%) in bisoxazoline/copper mediated ATRP of MMA in HFIP is described.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Science and Technology Commission of Shanghai Municipality

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2018/PY/C8PY00953H

Reference49 articles.

1. Atom Transfer Radical Polymerization (ATRP): Current Status and Future Perspectives

2. Controlled/living radical polymerization

3. Controlled/living radical polymerization: Features, developments, and perspectives

4. Atom Transfer Radical Polymerization

5. Transition Metal-Catalyzed Living Radical Polymerization: Toward Perfection in Catalysis and Precision Polymer Synthesis

Cited by 11 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. The Regulation of Stereoselectivity in Radical Polymerization^★;Acta Chimica Sinica;2024

2. SaBOX/Copper-Catalyzed Synthesis, Degradation, and Upcycling of a PMMA-Based Copolymer;Macromolecules;2023-08-23

3. Hydrogen Bond Effects: A Strategy for Improving Controllability in Organocatalytic Photoinduced Controlled Radical Polymerization Targeting High Molecular Weight;ACS Catalysis;2022-09-09

4. Reversible complexation mediated polymerization: an emerging type of organocatalytically controlled radical polymerization;Polymer Chemistry;2022

5. Chain flexibility and glass transition temperatures of poly(n-alkyl (meth)acrylate)s: Implications of tacticity and chain dynamics;Polymer;2021-01