Scalable anti-Markovnikov hydrobromination of aliphatic and aromatic olefins
Author:
Affiliation:
1. Chemistry
2. University of Southampton
3. Southampton
4. UK
5. School of Biological and Chemical Sciences
6. Queen Mary University of London
7. London
Abstract
A simple synthesis of primary bromides from alkenes using HBr in AcOH and atmospheric oxygen as a radical initiator.
Funder
Engineering and Physical Sciences Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/OB/C6OB00692B
Reference41 articles.
1. H. C. Brown , Hydroboration, W. A. Benjamin, New York, 1962
2. H. C. Brown , (with techniques by G. W. Kramer, A. B. Levy, M. M. Midland), Organic Syntheses via Boranes, Wiley-Interscience, New York, 1975
3. Asymmetric Conjugate Additions and Allylic Alkylations Using Nucleophiles Generated by Hydro- or Carbometallation
4. I. Ueber die Abhängigkeit der verschiedenen Vertretbarkeit des Radicalwasserstoffs in den isomeren Buttersäuren
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