Isomerization of a lanthanide complex using a humming top guest template: a solid-to-solid reaction

Author:

Mills Michelle B.123,Hollingshead Andrew G.123,Maahs Adam C.123,Soldatov Dmitriy V.123,Preuss Kathryn E.123

Affiliation:

1. Department of Chemistry

2. University of Guelph

3. Guelph, Canada

Abstract

SbPh3Cl2is used to effect a dramatic rearrangement of the ligand sphere and “pancake bonding” in Ce(hfac)3(5′-Br-pyDTDA)2by forming a 2 : 1 host–guest complex.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Reference53 articles.

1. Cyclic polyethers and their complexes with metal salts

2. Diaza-polyoxa-macrocycles et macrobicycles

3. J. B. Wittenberg and L.Isaacs, in Supramolecular Chemistry: From Molecules to Nanomaterials, ed. P. A. Gale and J. W. Steed, John Wiley & Sons, Ltd., 2012, vol. 1, p. 25

4. The Design of Molecular Hosts, Guests, and Their Complexes (Nobel Lecture)

5. The Cucurbit[n]uril Family

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