Advances in transition metal-free deborylative transformations of gem-diborylalkanes

Author:

Jo Woohyun1234ORCID,Lee Jun Hee5674ORCID,Cho Seung Hwan1234ORCID

Affiliation:

1. Department of Chemistry

2. Pohang University of Science and Technology

3. Pohang

4. Republic of Korea

5. Department of Advanced Materials Chemistry

6. Dongguk University – Gyeongju Campus

7. Gyeongju, Gyeongsangbuk-do

Abstract

This article highlights recent advances on the base-promoted deborylative carbon–carbon and carbon–boron bond-forming reactions using gem-diborylalkanes as the sources of α-borylcabanions.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference103 articles.

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3. K. Vollhardt and N.Schore , Organic Chemistry: Structure and Function , W. H. Freeman , New York , 2014

4. The Chemistry of Organomagnesium Compounds , ed. Z. Rappoport and I. Marek , Wiley-VCH , Weinheim, Germany , 2008

5. S. J. Blanksby and J. H.Bowie , “Carbanions: formation, structure and thermochemistry”, The encyclopedia of mass spectrometry , ed. M. L. Gross and R. M. Caprioli , Elsevier , Amsterdam , 1st edn, 2005

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