Redox and guest tunable spin-crossover properties in a polymeric polyoxometalate

Author:

Palacios-Corella Mario1ORCID,García-López Víctor1,Waerenborgh Joao Carlos2ORCID,Vieira Bruno J. C.2ORCID,Mínguez Espallargas Guillermo1ORCID,Clemente-León Miguel1ORCID,Coronado Eugenio1ORCID

Affiliation:

1. Instituto de Ciencia Molecular (ICMol), Universitat de València, C/Catedrático José Beltrán 2, 46980 Paterna, Spain

2. Centro de Ciências e Tecnologias Nucleares, DECN, Instituto Superior Técnico, Universidade de Lisboa, 2695-066 Bobadela LRS, Portugal

Abstract

1D coordination polymers with hexavanadates and spin-crossover units lead to a compound in which spin transition coexists with the redox properties of the polyoxometalates and can be tuned by temperature, light, solvent exchange or redox processes.

Funder

Ministerio de Ciencia e Innovación

H2020 European Research Council

Generalitat Valenciana

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference52 articles.

1. Spin Crossover in Transition Metal Compounds, Topics in Current Chemistry , ed. P. Gütlich and H. A. Goodwin , Springer Verlag , Berlin-Heidelberg-New York , 2004 , vol. 233–235

2. Spin-Crossover Materials: Properties and Applications , ed. M. A. Halcrow , John Wiley & Sons , Chichester, UK , 2013

3. Emerging trends in spin crossover (SCO) based functional materials and devices

4. Spin crossover polymer composites, polymers and related soft materials

5. Molecular magnetism: from chemical design to spin control in molecules, materials and devices

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