CBe<sub>4</sub>H<sub>6</sub>: a molecular rotor with a built-in on–off switch-Reference-Cited by-同舟云学术

CBe₄H₆: a molecular rotor with a built-in on–off switch

Published:2024 Issue:9 Volume:16 Page:4778-4786
ISSN:2040-3364
Container-title:Nanoscale
language:en
Short-container-title:Nanoscale

Author:

Jin Bo¹²³^ORCID,Yuan Caixia¹²^ORCID,Guo Jin-Chang¹²^ORCID,Wu Yan-Bo¹²^ORCID

Affiliation:

1. Key Laboratory of Materials for Energy Conversion and Storage of Shanxi Province, Institute of Molecular Science, Shanxi University, 92 Wucheng Road, Taiyuan, Shanxi, 030006, People's Republic of China

2. Key Laboratory of Chemical Biology and Molecular Engineering of Ministry of Education, Institute of Molecular Science, Shanxi University, 92 Wucheng Road, Taiyuan, Shanxi, 030006, People's Republic of China

3. Department of Chemistry, Xinzhou Normal University, 1 East Dunqi Street, Xinzhou, Shanxi, 034000, People's Republic of China

Abstract

CBe4H6 is a molecular rotor with a C–H bond as on-off switch, the temperature-dependent equatorial and axial configurations of the C–H bond can stop and resume rotation, respectively, by destroying and restoring its central delocalized σ bonds.

Funder

National Natural Science Foundation of China

Shanxi University

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NR/D3NR05695C

Reference61 articles.

1. Artificial Molecular Machines

2. Computational design of mechanically coupled axle-rotor protein assemblies

3. Action of a minimal contractile bactericidal nanomachine

4. Nanomotor rotates microscale objects

5. An Intelligent Nanomachine Guided by DNAzyme Logic System for Precise Chemodynamic Therapy

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Dynamic Structural Fluxionality in a Planar Tetracoordinate Carbon Cluster Stabilized by Boron Ligands;Chemistry – A European Journal;2024-08-22

2. In_nTl_4–nH⁺ (n = 0∼4): Tetracoordinate Hydrogen in a Planar Fashion?;Inorganic Chemistry;2024-07-12