Optimized molecular aggregation and photophysical process synergistically promoted photovoltaic performance in low-regularity benzo[c][1,2,5]thiadiazole-based medium-bandgap copolymers via modulating π bridges

Author:

Tong Junfeng1ORCID,Huang Yubo1,Liu Wuyan1,Shou Mengdie1,An Lili2,Jiang Xuefeng1,Guo Pengzhi1,Han Yang3,Liang Zezhou4,Li Jianfeng1ORCID,Xia Yangjun1ORCID

Affiliation:

1. Gansu Provincial Engineering Research Center for Organic Semiconductor Materials and Application Technology, School of Materials Science and Engineering, Lanzhou Jiaotong University, Lanzhou, 730070, China

2. School of Chemical Engineering, Northwest Minzu University, Lanzhou, 730030, China

3. School of Materials Science and Engineering, Tianjin University, Tianjin, 300072, China

4. Key Laboratory for Physical Electronics and Devices of the Ministry of Education & Shaanxi Key Lab of Information Photonic Technique, School of Electronics and Information Engineering, Xi’an Jiaotong University, Xi’an, 710049, China

Abstract

Low regularity PClBDT-TBT not only effectively improved molecular aggregation but also prolonged exciton diffusion time in order to suppress recombination and ameliorate charge transfer, leading to an excellent PCE of 13.04% when paired with Y6.

Funder

Natural Science Foundation of Gansu Province

National Natural Science Foundation of China

Support Program for Longyuan Youth and Fundamental Research Funds for the Universities of Gansu Province

Lanzhou Jiaotong University

Tianjin University of Technology

Foundation for Innovation Groups of Basic Research in Gansu Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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