Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes-Reference-Cited by-同舟云学术

Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes

Published:2021 Issue:54 Volume:57 Page:6640-6643
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Dierks Philipp¹²³⁴⁵,Kruse Ayla⁶⁷⁸⁹⁵,Bokareva Olga S.⁶⁷⁸⁹⁵^ORCID,Al-Marri Mohammed J.⁶⁷⁸⁹⁵^ORCID,Kalmbach Jens¹⁰¹¹¹²⁵,Baltrun Marc¹²³⁴⁵,Neuba Adam¹²³⁴⁵,Schoch Roland¹²³⁴⁵^ORCID,Hohloch Stephan¹³¹⁴¹⁵¹⁶¹⁷^ORCID,Heinze Katja¹⁸¹⁹²⁰²¹⁵^ORCID,Seitz Michael¹⁰¹¹¹²⁵^ORCID,Kühn Oliver⁶⁷⁸⁹⁵^ORCID,Lochbrunner Stefan⁶⁷⁸⁹⁵^ORCID,Bauer Matthias¹²³⁴⁵^ORCID

Affiliation:

1. Faculty of Science

2. Chemistry Department and Centre for Sustainable Systems Design

3. Paderborn University

4. 33098 Paderborn

5. Germany

6. Institute of Physics and Department of Life

7. Light and Matter

8. University of Rostock

9. 18051 Rostock

10. Institute of Inorganic Chemistry

11. University of Tübingen

12. 72076 Tübingen

13. University of Innsbruck

14. Faculty of Chemistry and Pharmacy

15. Institute for General

16. Inorganic and Theoretical Chemistry

17. Innsbruck 6020

18. Department of Chemistry

19. Johannes Gutenberg

20. University of Mainz

21. 55128 Mainz

Abstract

The photodynamics of two pseudoisomeric iron(ii) complexes reveal insights into reactive metal-centred states and hot branching dynamics. A new type of reactivity by triplet energy transfer from MC states enables oxygen sensitization activity.

Funder

Deutsche Forschungsgemeinschaft

Ministry of Education and Science of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC01716K

Reference27 articles.

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4. Fe N-Heterocyclic Carbene Complexes as Promising Photosensitizers

5. Synthesis and Characterization of a High-Symmetry Ferrous Polypyridyl Complex: Approaching the 5T2/3T1 Crossing Point for FeII

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