Parasitic crystallization of colloidal electrolytes: growing a metastable crystal from the nucleus of a stable phase

Author:

Sanchez-Burgos Ignacio12345ORCID,Garaizar Adiran12345ORCID,Vega Carlos678910ORCID,Sanz Eduardo678910ORCID,Espinosa Jorge R.12345ORCID

Affiliation:

1. Maxwell Centre

2. Cavendish Laboratory

3. Department of Physics

4. University of Cambridge

5. J J Thomson Avenue

6. Departamento de Quimica Fisica

7. Facultad de Ciencias Quimicas

8. Universidad Complutense de Madrid

9. 28040 Madrid

10. Spain

Abstract

Despite its lower stability and higher nucleation barrier, a metastable charge-disordered colloidal phase manages to parasitically crystallize from nuclei of the stable charge-ordered phase due to its enhanced kinetic crystal growth.

Funder

Engineering and Physical Sciences Research Council

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Chemistry

Reference120 articles.

1. K. F. Kelton , Crystal Nucleation in Liquids and Glasses , Academic , Boston , 1991

2. P. G. Debenedetti , Metastable liquids: Concepts and Principles , Princeton University Press , 1996

3. Crystal Nucleation in Liquids: Open Questions and Future Challenges in Molecular Dynamics Simulations

4. Real-Space Imaging of Nucleation and Growth in Colloidal Crystallization

5. Ice nucleation rates near ∼225 K

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