Parasitic crystallization of colloidal electrolytes: growing a metastable crystal from the nucleus of a stable phase
Author:
Affiliation:
1. Maxwell Centre
2. Cavendish Laboratory
3. Department of Physics
4. University of Cambridge
5. J J Thomson Avenue
6. Departamento de Quimica Fisica
7. Facultad de Ciencias Quimicas
8. Universidad Complutense de Madrid
9. 28040 Madrid
10. Spain
Abstract
Despite its lower stability and higher nucleation barrier, a metastable charge-disordered colloidal phase manages to parasitically crystallize from nuclei of the stable charge-ordered phase due to its enhanced kinetic crystal growth.
Funder
Engineering and Physical Sciences Research Council
Ministerio de Economía y Competitividad
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/SM/D0SM01680B
Reference120 articles.
1. K. F. Kelton , Crystal Nucleation in Liquids and Glasses , Academic , Boston , 1991
2. P. G. Debenedetti , Metastable liquids: Concepts and Principles , Princeton University Press , 1996
3. Crystal Nucleation in Liquids: Open Questions and Future Challenges in Molecular Dynamics Simulations
4. Real-Space Imaging of Nucleation and Growth in Colloidal Crystallization
5. Ice nucleation rates near ∼225 K
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