Magnetic study and DFT analysis of a doubly carboxylato-bridged Co(<scp>ii</scp>) derivative anchored with a ‘scorpionate’ precursor as a potential electrocatalyst for heterogeneous H<sub>2</sub> evolution-Reference-Cited by-同舟云学术

Magnetic study and DFT analysis of a doubly carboxylato-bridged Co(ii) derivative anchored with a ‘scorpionate’ precursor as a potential electrocatalyst for heterogeneous H₂ evolution

Published:2024 Issue:22 Volume:53 Page:9358-9368
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Das Kuheli¹²,Beyene Belete B.³²^ORCID,Massera Chiara⁴^ORCID,Garribba Eugenio⁵^ORCID,El Fallah M. S.⁶,Frontera Antonio⁷^ORCID,Hung Chen-Hsiung²,Datta Amitabha²⁸^ORCID

Affiliation:

1. Department of Chemistry, University of Calcutta, 92 A.P.C. Road, Kolkata - 700009, India

2. Institute of Chemistry, Academia Sinica, Nankang – 115, Taipei, Taiwan

3. Department of Chemistry, Bahir Dar University, P.O. Box 79, Bahir Dar, Ethiopia

4. Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale, Università degli Studi di Parma, Viale delle Scienze 17/A, 43124 Parma, Italy

5. Dipartimento di Medicina, Chirurgia e Farmacia, Università di Sassari, Viale San Pietro, I-07100 Sassari, Italy

6. Departament de Química Inorgànica i Orgànica, Secció Inorgànica and Institut de Nanociència i Nanotecnologia, Universitat de Barcelona, Martí i Franquès, 1-11, 08028-Barcelona, Spain

7. Departament de Química, Universitat de les Illes Balears, Crta de Valldemossa km 7.5, 07122 Palma de Mallorca, Baleares, Spain

8. Department of Chemistry, National Changhua University of Education, Changhua – 50058, Taiwan

Abstract

A new doubly carboxylato-bridged Co(ii) dinuclear complex, [Co(bdtbpza)(NCS)]2 (1), was obtained in a satisfactory yield by employing a ‘scorpionate’-type precursor, bdtbpza {bis-(3,5-di-tert-butylpyrazol-1-yl)acetate}, and was then structurally characterized.

Funder

Science and Engineering Research Board

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00807C

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