Isolating elusive ‘Al(μ-O)M’ intermediates in CO<sub>2</sub> reduction by bimetallic Al–M complexes (M = Zn, Mg)-Reference-Cited by-同舟云学术

Isolating elusive ‘Al(μ-O)M’ intermediates in CO₂ reduction by bimetallic Al–M complexes (M = Zn, Mg)

Published:2022 Issue:72 Volume:58 Page:10091-10094
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Evans Matthew J.¹,Iliffe George H.¹,Neale Samuel E.²^ORCID,McMullin Claire L.²^ORCID,Fulton J. Robin¹^ORCID,Anker Mathew D.¹^ORCID,Coles Martyn P.¹^ORCID

Affiliation:

1. School of Chemical and Physical Sciences, Victoria University of Wellington, P.O. Box 600, Kelburn, Wellington, 6012, New Zealand

2. Department of Chemistry, University of Bath, Bath, BA2 7AY, UK

Abstract

We confirm that the μ-oxo species (NONDipp)Al(μ-O)M(BDIMes) are viable intermediates in the conversion of CO2 to carbonate promoted by bimetallic Al–Mg and Al–Zn compounds.

Funder

Engineering and Physical Sciences Research Council

Royal Society Te Apārangi

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC04028J

Reference40 articles.

1. Main group bimetallic partnerships for cooperative catalysis

2. Alkali‐Metal Mediation: Diversity of Applications in Main‐Group Organometallic Chemistry

3. Bimetallic cooperation across the periodic table

4. Alkali-Metal-Mediated Synergistic Effects in Polar Main Group Organometallic Chemistry

5. Metal–Metal Bonds in Catalysis

Cited by 20 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. The Ether‐Adduct of a Lewis Superacidic, Dicoordinate Aluminum Hydride Cation and the Ion Affinities of Solvent‐Adducts;Zeitschrift für anorganische und allgemeine Chemie;2024-08-04

2. Aluminium(I) anion-supported zero-valent palladium complexes;Nature Synthesis;2024-05-16

3. Bis(Aluminyl)Magnesium: A Source of Nucleophilic or Radical Aluminium‐Centred Reactivity;Angewandte Chemie International Edition;2024-04-22

4. Mercury‐Group 13 Metal Covalent Bonds: A Systematic Comparison of Aluminyl, Gallyl and Indyl Metallo‐ligands;Angewandte Chemie International Edition;2024-04-22

5. Bis(Aluminyl)Magnesium: A Source of Nucleophilic or Radical Aluminium‐Centred Reactivity;Angewandte Chemie;2024-04-22