Synthesis of hyperbranched low molecular weight polyethylene oils by an iminopyridine nickel(ii) catalyst

Author:

D'Auria Ilaria1234ORCID,Milione Stefano1234ORCID,Caruso Tonino1234ORCID,Balducci Gabriele5674ORCID,Pellecchia Claudio1234ORCID

Affiliation:

1. Dipartimento di Chimica e Biologia “A. Zambelli”

2. Università di Salerno

3. I-84084 Fisciano

4. Italy

5. Dipartimento di Scienze Chimiche e Farmaceutiche

6. Università di Trieste

7. I-34127 Trieste

Abstract

A 6-(2,6-dimethylphenyl)-2-(2,6-diisopropylphenyl)iminopyridine dibromo nickel(ii) complex was synthesized, characterized by X-ray diffraction analysis and tested in ethylene polymerization using diethylaluminumchloride as the cocatalyst.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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