2-Bromo-6-(chlorodiisopropylsilyl)phenyl tosylate as an efficient platform for intramolecular benzyne–diene [4 + 2] cycloaddition-Reference-Cited by-同舟云学术

2-Bromo-6-(chlorodiisopropylsilyl)phenyl tosylate as an efficient platform for intramolecular benzyne–diene [4 + 2] cycloaddition

Published:2019 Issue:13 Volume:10 Page:3840-3845
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Nishii Arata¹²³⁴,Takikawa Hiroshi⁵⁶⁷⁴^ORCID,Suzuki Keisuke¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Tokyo Institute of Technology

3. Tokyo 152-8551

4. Japan

5. Graduate School of Pharmaceutical Sciences

6. Kyoto University

7. Kyoto 606-8501

Abstract

An intramolecular benzyne–diene [4 + 2] cycloaddition with broad substrate scope has been realized by using a cleavable silicon tether, allowing access to various polycyclic structures.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C8SC05518A

Reference78 articles.

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