Identification of vanadium dopant sites in the metal–organic framework DUT-5(Al)-Reference-Cited by-同舟云学术

Identification of vanadium dopant sites in the metal–organic framework DUT-5(Al)

Published:2021 Issue:12 Volume:23 Page:7088-7100
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Maes Kwinten¹²³⁴^ORCID,Martin Lisa I. D. J.¹²³⁴^ORCID,Khelifi Samira¹²³⁴,Hoffman Alexander⁵⁶⁷⁴^ORCID,Leus Karen⁸²³⁴^ORCID,Van Der Voort Pascal⁸²³⁴^ORCID,Goovaerts Etienne⁹¹⁰¹¹⁴,Smet Philippe F.¹²³⁴^ORCID,Van Speybroeck Veronique⁵⁶⁷⁴^ORCID,Callens Freddy¹²³⁴^ORCID,Vrielinck Henk¹²³⁴^ORCID

Affiliation:

1. Department of Solid State Sciences

2. Ghent University

3. B-9000 Gent

4. Belgium

5. Center for Molecular Modeling

6. Ghent University, Tech Lane Ghent Science Park Campus A, Technologiepark 46

7. 9052 Zwijnaarde

8. Department of Chemistry

9. Department of Physics

10. University of Antwerp

11. B-2610 Antwerp

Abstract

EPR spectra of V-doped DUT-5(Al) reveal four types of paramagnetic dopant species. Spin-Hamiltonian analysis and spectrum decomposition as function of V-content are supplemented with structural information from other spectroscopic techniques.

Funder

Fonds Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP00695A

Reference45 articles.

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2. EPR characterization of vanadium dopant sites in DUT-5(Al)

3. Discovery of a novel, large pore phase in a bimetallic Al/V metal–organic framework

4. Luminescent metal–organic frameworks for chemical sensing and explosive detection

5. The remarkable catalytic activity of the saturated metal organic framework V-MIL-47 in the cyclohexene oxidation

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