Water-promoted ortho-selective monohydroxymethylation of phenols in the NaBO2 system
Author:
Affiliation:
1. School of Marine Science and Technology
2. Harbin Institute of Technology at Weihai
3. Shandong 264209, China
4. Beijing National Laboratory for Molecular Sciences (BNLMS)
5. and Key Laboratory of Molecular Recognition and Function
Abstract
Water-promoted ortho-selective monohydroxymethylation of phenols in the NaBO2 system generates salicyl alcohols in excellent yields.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/OB/C4OB00228H
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1. All-Carbon Quaternary Centers via Ruthenium-Catalyzed Hydroxymethylation of 2-Substituted Butadienes Mediated by Formaldehyde: Beyond Hydroformylation
2. Organocatalytic Enantioselective Hydroxymethylation of Oxindoles with Paraformaldehyde as C1 Unit
3. Black-Light-Induced Radical/Ionic Hydroxymethylation of Alkyl Iodides with Atmospheric CO in the Presence of Tetrabutylammonium Borohydride
4. Direct asymmetric α-hydroxymethylation of ketones in homogeneous aqueous solvents
5. A contribution to the study of the modified Marschalk reaction: Hydroxymethylation of 6,8-O-dimethyl emodin
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