A combined experimental and theoretical study of optical rotatory dispersion for (R)-glycidyl methyl ether in aqueous solution

Author:

Egidi Franco123ORCID,Giovannini Tommaso123ORCID,Del Frate Gianluca123ORCID,Lemler Paul M.4567,Vaccaro Patrick H.4567ORCID,Cappelli Chiara123ORCID

Affiliation:

1. Scuola Normale Superiore

2. Pisa

3. Italy

4. Department of Chemistry

5. Yale University

6. New Haven

7. USA

Abstract

We present a theoretical-experimental study of the optical rotation of (R)-glycidylmethylether using a mixed quantum-classical model for solvent effects.

Funder

Division of Chemistry

H2020 Marie Skłodowska-Curie Actions

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference63 articles.

1. T. M. Lowry , Optical Rotatory Power , Longmans, Green and Company , London , 1935

2. Comprehensive Chiroptical Spectroscopy , ed. N. Berova , P. L. Polavarapu , K. Nakanishi and R. W. Woody , John Wiley & Sons , Hoboken, NJ , 2012

3. L. Barron , Molecular Light Scattering and Optical Activity , Cambridge University Press , Cambridge , 2nd edn, 2004

4. P. H. Vaccaro , Comprehensive Chiroptical Spectroscopy , John Wiley & Sons , Hoboken, NJ , 2012 , ch. 11, pp. 275–323

5. Large Solvation Effect in the Optical Rotatory Dispersion of Norbornenone

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