Structure and stability of CaH2surfaces: on the possibility of electron-rich surfaces in metal hydrides for catalysis-Reference-Cited by-同舟云学术

Structure and stability of CaH2surfaces: on the possibility of electron-rich surfaces in metal hydrides for catalysis

Published:2017 Issue:11 Volume:5 Page:5550-5558
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Ong Phuong-Vu¹²³⁴⁵^ORCID,Johnson Lewis E.¹²³⁴⁵,Hosono Hideo⁶⁷⁸⁹,Sushko Peter V.¹²³⁴⁵

Affiliation:

1. Physical Sciences Division

2. Physical & Computational Sciences Directorate

3. Pacific Northwest National Laboratory

4. Richland

5. USA

6. Materials Research Center of Element Strategy

7. Tokyo Institute of Technology

8. Yokohama 226-8053

9. Japan

Abstract

Thermally activated CaH₂hosts a high concentration of localized electrons which can promote reactions that require multi-electron transfer to break or make chemical bonds.

Funder

Japan Science and Technology Agency

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/TA/C6TA09561E

Reference56 articles.

1. Light-induced conversion of an insulating refractory oxide into a persistent electronic conductor

2. Photoinduced generation of electron anions in H-doped nanoporous oxide 12CaO∙7Al2O3: Toward an optically controlled formation of electrides

3. Hydride Ion as a Two-Electron Donor in a Nanoporous Crystalline Semiconductor 12CaO·7Al2O3

4. Ammonia synthesis using a stable electride as an electron donor and reversible hydrogen store

5. The Hydride Anion in an Extended Transition Metal Oxide Array: LaSrCoO 3 H 0.7

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