Unexpected triaxial preferences in some all-<i>syn</i> 1,3,5-trifluorocyclohexanes-Reference-Cited by-同舟云学术

Unexpected triaxial preferences in some all-syn 1,3,5-trifluorocyclohexanes

Published:2022 Issue:92 Volume:58 Page:12855-12858
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Yu Cihang¹,Piscelli Bruno A.²,Maharik Nawaf Al³^ORCID,Cordes David B.¹^ORCID,Slawin Alexandra M. Z.¹^ORCID,Cormanich Rodrigo A.²^ORCID,O'Hagan David¹^ORCID

Affiliation:

1. University of St Andrews, School of Chemistry, North Haugh, St Andrews, Fife, KY16 9ST, UK

2. University of Campinas, Chemistry Institute, Monteiro Lobato Street, Campinas, Sao Paulo, 13083-862, Brazil

3. Department of Chemistry, Faculty of Science, An Najah National University, Nablus, Palestine

Abstract

Theory and solution NMR indicate that all-syn 1,3,5-trifluorocyclohexane adopts the expected tri-equatorial conformation, however in the solid state the more polar triaxial conformation is observed.

Funder

China Scholarship Council

Fundação de Amparo à Pesquisa do Estado de São Paulo

Fundo de Apoio ao Ensino, à Pesquisa e Extensão, Universidade Estadual de Campinas

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC05058G

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5. Fluorinated Rings: Conformation and Application

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