Affiliation:
1. Research School of Chemistry, Australian National University, Acton, ACT, 2601, Australia
Abstract
Electrophilic or nucleophilic? Reduction of a bulky boron bromide with lithium leads to C–N bond cleavage though a nucleophilic boryl anion. In contrast, reaction with an anionic iron carbonyl salt leads to cooperative reduction of CO.
Funder
Australian Research Council
National Computational Infrastructure
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis
Reference36 articles.
1. Boryllithium: Isolation, Characterization, and Reactivity as a Boryl Anion
2. M.Yamashita and K.Nozaki , in Boryl Anions: Synthesis and Application of Organoboron Compounds. Topics in Organometallic Chemistry , ed. E. Fernández and A. Whiting , Springer , Cham , 2015 , vol. 49
3. 1,3,2‐Diazaborolyl Anions – From Laboratory Curiosities to Versatile Reagents in Synthesis
4. M.Yamashita in Chemistry of Boryl Anions: Recent Developments , ed. A. E. H. Wheatley and M. Uchiyama , John Wiley and Sons , New York , 2022
5. Chemistry of Boryllithium: Synthesis, Structure, and Reactivity