Odd–even effects in aryl-substituted alkanethiolate SAMs: nonsymmetrical attachment of aryl unit and its impact on the SAM structure

Author:

Azzam Waleed1ORCID,Subaihi Abdu2,Rohwerder Michael3ORCID,Bashir Asif4,Terfort Andreas5ORCID,Zharnikov Michael6ORCID

Affiliation:

1. Department of Chemistry, Tafila Technical University, P.O. Box 179, Tafila-66110, Jordan

2. Department of Chemistry, University College in Al-Qunfudah, Umm Al-Qura University, 1109 Makkah Al-Mukarramah, Saudi Arabia

3. Max-Planck-Institut fuer Eisenforschung GmbH, Max-Planck-Str. 1, 40237 Düsseldorf, Germany

4. Thyssenkrupp Bilstein GmbH, Thyssenkrupp Allee 1, 45143 Essen, Germany

5. Institute of Inorganic and Analytical Chemistry, Goethe-University, D-60438 Frankfurt, Germany

6. Applied Physical Chemistry, Heidelberg University, Im Neuenheimer Feld 253, D-69120 Heidelberg, Germany

Abstract

Due to non-symmetric attachment of the anthracene unit to the alkanethiolate linker, the respective monolayers on Au(111) exhibit low extent of the odd–even effects and distinct polymorphism, showing, at the same time, high structural order.

Publisher

Royal Society of Chemistry (RSC)

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