Phosphorous(v) Lewis acids: water/base tolerant P3-trimethylated trications-Reference-Cited by-同舟云学术

Phosphorous(v) Lewis acids: water/base tolerant P3-trimethylated trications

Published:2018 Issue:88 Volume:54 Page:12467-12470
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Bayne J. M.¹²³,Fasano V.¹²³⁴⁵^ORCID,Szkop K. M.¹²³^ORCID,Ingleson M. J.⁴⁵⁶^ORCID,Stephan D. W.¹²³^ORCID

Affiliation:

1. Department of Chemistry

2. University of Toronto

3. Canada

4. School of Chemistry

5. University of Manchester

6. UK

Abstract

The water/base intolerance of the previously reported electrophilic phosphonium cations has been overcome by replacing the labile electron-withdrawing groups generally attached to phosphorus (e.g. –F, –OAr, –CF₃) with methyl groups.

Funder

Royal Society of Chemistry

Natural Sciences and Engineering Research Council of Canada

Engineering and Physical Sciences Research Council

University of Manchester

Canada Research Chairs

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC06564K

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3. N-Methylacridinium Salts: Carbon Lewis Acids in Frustrated Lewis Pairs for σ-Bond Activation and Catalytic Reductions

4. N-Methyl-Benzothiazolium Salts as Carbon Lewis Acids for Si−H σ-Bond Activation and Catalytic (De)hydrosilylation

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