Stereoselective synthesis of 1,6-dioxaspirolactones from spiro-cyclopropanecarboxylated sugars: total synthesis of dihydro-pyrenolide D-Reference-Cited by-同舟云学术

Stereoselective synthesis of 1,6-dioxaspirolactones from spiro-cyclopropanecarboxylated sugars: total synthesis of dihydro-pyrenolide D

Published:2015 Issue:11 Volume:5 Page:8142-8145
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Ramakrishna Bandi¹²³⁴,Sridhar Perali Ramu¹²³⁴

Affiliation:

1. School of Chemistry

2. University of Hyderabad

3. Hyderabad – 500 046

4. India

Abstract

A one-pot protocol for the stereoselective construction of γ-spiroketal γ-lactone frameworks from sugar derived spiro-cyclopropanecarboxylic acids involving a ring enlargement and cyclization reaction is revealed.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C4RA16753H

Reference50 articles.

1. Chemistry of spiroketals

2. Nonanomeric Spiroketals in Natural Products: Structures, Sources, and Synthetic Strategies

3. Lancifodilactone G: A Unique Nortriterpenoid Isolated from Schisandra lancifolia and Its Anti-HIV Activity

4. Oxidative spirocyclisation routes towards the sawaranospirolides. Synthesis of ent-sawaranospirolides C and D

5. Synthesis of bis-spiroacetal ring systems

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