Stereoselective synthesis of 1,6-dioxaspirolactones from spiro-cyclopropanecarboxylated sugars: total synthesis of dihydro-pyrenolide D

Author:

Ramakrishna Bandi1234,Sridhar Perali Ramu1234

Affiliation:

1. School of Chemistry

2. University of Hyderabad

3. Hyderabad – 500 046

4. India

Abstract

A one-pot protocol for the stereoselective construction of γ-spiroketal γ-lactone frameworks from sugar derived spiro-cyclopropanecarboxylic acids involving a ring enlargement and cyclization reaction is revealed.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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