Mixed-metal chalcogenide tetrahedral clusters with an exo-polyhedral metal fragment

Author:

Yuvaraj K.123,Roy Dipak Kumar123,Anju V. P.123,Mondal Bijnaneswar123,Varghese Babu423,Ghosh Sundargopal123

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Madras

3. Chennai 600 036, India

4. Sophisticated Analytical Instruments Facility

Abstract

Mixed-metal chalcogenide tetrahedral clusters, [Cp*Ru(CO)2(μ-H){Os3(CO)9}S] and [Cp*Ru(CO)2(μ-H){Ru3(CO)9}S], have been isolated from arachno-[(Cp*RuCO)2B2H6] and [(Cp*Mo)2B5H9] respectively, in which the [Cp*Ru(CO)2] fragment is attached in an exo-polyhedral manner.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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3. Metal Clusters in Chemistry , ed. P. Braunstein , L. A. Oro and P. R. Raithby , Wiley-VCH , Weinheim , 1999

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5. Crystallographic studies of transition metal hydride complexes

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