Stabilization <i>versus</i> competing de-metalation, trans-metalation and (cyclo)-dehydrogenation of Pd porphyrins at a copper surface-Reference-Cited by-同舟云学术

Stabilization versus competing de-metalation, trans-metalation and (cyclo)-dehydrogenation of Pd porphyrins at a copper surface

Published:2024 Issue:28 Volume:16 Page:13416-13424
ISSN:2040-3364
Container-title:Nanoscale
language:en
Short-container-title:Nanoscale

Author:

Baronio Stefania¹,Bassotti Mattia²^ORCID,Armillotta Francesco¹³,Frampton Eleanor⁴,Vinogradov Nikolay A.⁴^ORCID,Schio Luca⁵^ORCID,Floreano Luca⁵^ORCID,Verdini Alberto²⁵^ORCID,Vesselli Erik¹⁵⁶^ORCID

Affiliation:

1. Department of Physics, University of Trieste, Trieste, Italy

2. Department of Physics, University of Perugia, Perugia, Italy

3. Institute of Physics Ecole Polytechnique Fédérale de Lausanne (EPFL) Station 3, Lausanne, Switzerland

4. MAX IV Laboratory, Lund, Sweden

5. CNR-IOM – Istituto Officina dei Materiali, Area Science Park, Trieste, Italy

6. Center for Energy, Environment and Transport Giacomo Ciamician, University of Trieste, Trieste, Italy

Abstract

Competition with de-metalation, trans-metalation and (cyclo)-dehydrogenation of Pd porphyrins at a copper surface can be tuned by means of an oxygen decoupling layer, which stabilizes the pristine PdTPP species.

Funder

Ministero dell'Università e della Ricerca

European Commission

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NR/D4NR00699B

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