Imidosulfonate scorpionate ligands in lanthanide single-molecule magnet design: slow magnetic relaxation and butterfly hysteresis in [ClDy{Ph2PCH2S(NtBu)3}2]-Reference-Cited by-同舟云学术

Imidosulfonate scorpionate ligands in lanthanide single-molecule magnet design: slow magnetic relaxation and butterfly hysteresis in [ClDy{Ph2PCH2S(NtBu)3}2]

Published:2021 Issue:46 Volume:50 Page:17194-17201
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Jung Jochen¹,Legendre Christina M.¹^ORCID,Demeshko Serhiy¹,Herbst-Irmer Regine¹^ORCID,Stalke Dietmar¹^ORCID

Affiliation:

1. Georg-August Universität Göttingen, Institut für Anorganische Chemie, Tammannstraße 4, 37077 Göttingen, Germany

Abstract

In lanthanide SMM ligand design the [Ph2PCH2S(NtBu)3]− anion proved to be advantageous as the S–N bonds adapt easily to various metals. So, the dysprosium complex is a zero-field SMM (Ueff = 66 cm−1) with a butterfly hysteresis closing at 3.5 K.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT03555J

Reference53 articles.

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