Simple and reactive Ir(i) N-heterocyclic carbene complexes for alkyne activation-Reference-Cited by-同舟云学术

Simple and reactive Ir(i) N-heterocyclic carbene complexes for alkyne activation

Published:2019 Issue:13 Volume:48 Page:4333-4340
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Gatus Mark R. D.¹²³⁴^ORCID,Pernik Indrek¹²³⁴^ORCID,Tompsett Joshua A.¹²³⁴,Binding Samantha C.¹²³⁴,Peterson Matthew B.¹²³⁴⁵,Messerle Barbara A.¹²³⁴^ORCID

Affiliation:

1. Department of Molecular Sciences

2. Macquarie University

3. North Ryde

4. Australia

5. School of Chemistry

Abstract

Two simple unsymmetrical monometallic Ir(i) complexes with an N-heterocyclic carbene ligand were effective catalysts for C–X (X = N or O) and Si–N bond formation reactions compared to an analogous Ir(i) bimetallic complex.

Funder

Australian Research Council

Macquarie University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00313D

Reference46 articles.

1. Carbon–heteroatom bond formation catalysed by organometallic complexes

2. Making carbon-nitrogen bonds in biological and chemical synthesis