Synthesis of planar chiral [2.2]paracyclophane-based bisoxazoline ligands bearing no central chirality and application to Cu-catalyzed asymmetric O–H insertion reaction
Author:
Affiliation:
1. Faculty of Pharmacy
2. Meijo University
3. Nagoya 468-8503
4. Japan
5. Division of Pharmaceutical Sciences
6. Graduate School of Medical Sciences
7. Kanazawa University
8. Kanazawa 920-1192
Abstract
C 2-symmetric planar chiral [2.2]paracyclophane-based bisoxazoline ligands effectively control the asymmetric induction during the Cu-catalyzed O–H insertion reaction of α-diazo esters.
Funder
Japan Society for the Promotion of Science
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB00452G
Reference30 articles.
1. Update 1 of: C2-Symmetric Chiral Bis(oxazoline) Ligands in Asymmetric Catalysis
2. The Asymmetric Ullmann Reaction. 2. The Synthesis of Enantiomerically Pure C2-Symmetric Binaphthyls
3. Homochiral 2,2′-bis(oxazolyl)-1,1′-binaphthyls as ligands for copper(I)-catalyzed asymmetric cyclopropanation
4. Efficient Synthesis of 1,1‘-Binaphthyl and 2,2‘-Bi-o-tolyl-2,2‘-bis(oxazoline)s and Preliminary Use for the Catalytic Asymmetric Allylic Oxidation of Cyclohexene
5. Transition-Metal-Catalyzed Enantioselective Heteroatom–Hydrogen Bond Insertion Reactions
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