Studies on the diastereoselective oxidation of 1-thio-β-d-glucopyranosides: synthesis of the usually less favoured RS sulfoxide as a single diastereoisomer-Reference-Cited by-同舟云学术

Studies on the diastereoselective oxidation of 1-thio-β-d-glucopyranosides: synthesis of the usually less favoured RS sulfoxide as a single diastereoisomer

Published:2015 Issue:6 Volume:13 Page:1904-1914
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Moya-López Juan Francisco¹²³⁴,Elhalem Eleonora¹²³⁴,Recio Rocío⁵⁶⁷⁸⁴,Álvarez Eleuterio¹²³⁴,Fernández Inmaculada⁵⁶⁷⁸⁴,Khiar Noureddine¹²³⁴

Affiliation:

1. Instituto de Investigaciones Químicas

2. C.S.I.C-Universidad de Sevilla

3. 41092 Sevilla

4. Spain

5. Departamento de Química Orgánica y Farmacéutica

6. Facultad de Farmacia

7. Universidad de Sevilla

8. 41012 Sevilla

Abstract

The exo-anomeric effect paves the way for the synthesis of the usually less favored R_S-β-sulfinyl glycoside as a single diastereoisomer.

Funder

Consejo Superior de Investigaciones Científicas

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C4OB02030H

Reference56 articles.

1. Recent Developments in the Synthesis and Utilization of Chiral Sulfoxides

2. Enantiopure sulfoxides: recent applications in asymmetric synthesis

3. I. Fernández and N.Khiar, in Organosulfur Chemistry in Asymmetric Synthesis, ed. T. Toru and C. Bolm, Wiley-VCH-Verlag, Weinheim, 2008, p. 265

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