Origin of site-selectivity of hydrogen atom transfer in carbohydrate C–H alkylations <i>via</i> photoredox catalysis-Reference-Cited by-同舟云学术

Origin of site-selectivity of hydrogen atom transfer in carbohydrate C–H alkylations via photoredox catalysis

Published:2024 Issue:8 Volume:11 Page:2269-2276
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Ji Yujie¹,Hu Lingfei¹,Gao Han¹,Wu Yan-Bo²^ORCID,Lv Xiangying¹,Lu Gang¹^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan, Shandong 250100, China

2. Key Lab for Materials of Energy Conversion and Storage of Shanxi Province and Key Lab of Chemical Biology and Molecular Engineering of Ministry of Education, Institute of Molecular Science, Shanxi University, Taiyuan, Shanxi 030006, China

Abstract

Two major factors, i.e., C–H σ orbital energy and C–H BDE, account for the HAT site-selectivity of carbohydrates with the quinuclidine radical cation.

Funder

National Natural Science Foundation of China

Taishan Scholar Project of Shandong Province

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO00073K

Reference71 articles.

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4. Recent Advances in Transition Metal-Catalyzed Glycosylation

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