Facile synthesis of an A3B-type phthalocyanine with a peripheral thiocatecholate binding group and its coordination to Ni(dppe): spectroscopy and theory
Author:
Affiliation:
1. Fachbereich Chemie
2. Philipps-Universität Marburg
3. Marburg 35032
4. Germany
Abstract
A single thiocatecholate group has been combined with a phthalocyanine and used to coordinate a [Ni(dppe)]2+ fragment to give the unprecedented title complex [(dppe)Ni(S2PcH2)].
Funder
Deutscher Akademischer Austauschdienst
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT02060E
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1. New avenues for ligand-mediated processes – expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands
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3. Enhanced Photochemical Hydrogen Production by a Molecular Diiron Catalyst Incorporated into a Metal–Organic Framework
4. Tuning the Excited-State Properties of Platinum(II) Diimine Dithiolate Complexes
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