Single transition metal atom centered clusters activating semiconductor surface lattice atoms for efficient solar fuel production

Author:

Zhang Kai12ORCID,Sun Chen1,Chen Tao3,Niu Fujun4,Huang Zhiyi1,Gao Qi1,Xu Cuiping1,Zhang Xingjian1,Pian Qixiang1,Che Kunhong1,Gao Lei5ORCID,Liu Xianglei12ORCID,Xuan Yimin12ORCID

Affiliation:

1. College of Energy and Power Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China

2. Key Laboratory of Thermal Management and Energy Utilization of Aviation Vehicles, Ministry of Industry and Information Technology, Nanjing 210016, China

3. Research Laboratory for Biomedical Optics and Molecular Imaging, CAS Key Laboratory of Health Informatics, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China

4. International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an 710049, China

5. Beijing Advanced Innovation Center for Materials Genome Engineering, Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China

Abstract

Atomically dispersed NiO6 clusters decorated on sulphide photocatalysts effectively activate the surface lattice atoms of sulphide semiconductors, resulting in a remarkable improvement in hydrogen production at a loading amount as low as 0.05 wt%.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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