New oxidovanadium(iv) complex with a BIAN ligand: synthesis, structure, redox properties and catalytic activity

Author:

Fomenko Iakov S.123,Gushchin Artem L.12345ORCID,Shul’pina Lidia S.6783ORCID,Ikonnikov Nikolay S.6783,Abramov Pavel A.123ORCID,Romashev Nikolay F.12345,Poryvaev Artem S.45395,Sheveleva Alena M.45395,Bogomyakov Artem S.953ORCID,Shmelev Nikita Y.12345,Fedin Matvey V.953ORCID,Shul’pin Georgiy B.10831112ORCID,Sokolov Maxim N.12345ORCID

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences

2. Novosibirsk 630090

3. Russia

4. Novosibirsk State University

5. 630090 Novosibirsk

6. Nesmeyanov Institute of Organoelement Compounds

7. Russian Academy of Sciences

8. Moscow 119991

9. International Tomography Center, Siberian Branch of Russian Academy of Sciences

10. Department of Dynamics of Chemical and Biologicl Processes, Semenov Institute of Chemical Physics, Russian Academy of Sciences

11. Chair of Chemistry and Physics, Plekhanov Russian University of Economics

12. Moscow 117997

Abstract

The combination of a new oxidovanadium(iv) complex1with pyrazine-2-carboxylic acid (PCA; a cocatalyst) affords a catalytic system for the efficient oxidation of saturated hydrocarbons.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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