Spatiotemporal coke formation over zeolite ZSM-5 during the methanol-to-olefins process as studied with operando UV-vis spectroscopy: a comparison between H-ZSM-5 and Mg-ZSM-5-Reference-Cited by-同舟云学术

Spatiotemporal coke formation over zeolite ZSM-5 during the methanol-to-olefins process as studied with operando UV-vis spectroscopy: a comparison between H-ZSM-5 and Mg-ZSM-5

Published:2018 Issue:6 Volume:8 Page:1632-1644
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Goetze Joris¹²³⁴⁵^ORCID,Weckhuysen Bert M.¹²³⁴⁵^ORCID

Affiliation:

1. Inorganic Chemistry and Catalysis

2. Debye Institute for Nanomaterials Science

3. Utrecht University

4. 3584 CG Utrecht

5. The Netherlands

Abstract

In this work, during the methanol-to-olefins (MTO) reaction, the formation of hydrocarbon pool species as well as the accumulation of coke and coke precursor molecules were monitored with operando UV-vis spectroscopy.

Funder

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CY/C7CY02459B

Reference50 articles.

1. The Mechanism of Methanol to Hydrocarbon Catalysis

2. Initial Carbon–Carbon Bond Formation during the Early Stages of the Methanol‐to‐Olefin Process Proven by Zeolite‐Trapped Acetate and Methyl Acetate

3. Formation Mechanism of the First Carbon-Carbon Bond and the First Olefin in the Methanol Conversion into Hydrocarbons