Hydrodehalogenation of organohalides by Et3SiH catalysed by group 4 metal complexes and B(C6F5)3-Reference-Cited by-同舟云学术

Hydrodehalogenation of organohalides by Et3SiH catalysed by group 4 metal complexes and B(C6F5)3

Published:2020 Issue:9 Volume:49 Page:2771-2775
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Dunlop David¹²³⁴,Pinkas Jiří¹²³⁴,Horáček Michal¹²³⁴,Žilková Naděžda¹²³⁴,Lamač Martin¹²³⁴^ORCID

Affiliation:

1. J. Heyrovský Institute of Physical Chemistry

2. The Czech Academy of Sciences

3. 18223 Prague 8

4. Czech Republic

Abstract

The use of the Et₃SiH/B(C₆F₅)₃ system for the activation of group 4 metal catalysts allows the efficient and selective catalytic hydrodefluorination of trifluorotoluenes.

Funder

Grantová Agentura České Republiky

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT00360C

Reference39 articles.

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5. Aromatic C–F Bond Activation by Rare-Earth-Metal Complexes

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