Intramolecular C(sp2)–C (sp2) bond formation between phenanthroline and β-diketone thiosemicarbazones in PtII complexes: crystal structures and computational studies-Reference-Cited by-同舟云学术

Intramolecular C(sp2)–C (sp2) bond formation between phenanthroline and β-diketone thiosemicarbazones in PtII complexes: crystal structures and computational studies

Published:2020 Issue:28 Volume:49 Page:9564-9567
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Gonçalves Ana C. R.¹²³⁴,Rettondin Andressa R.¹²³⁴,Oliveira Carolina G.⁵⁶⁷⁸⁴^ORCID,Patrocinio Antonio O. T.⁵⁶⁷⁸⁴^ORCID,Machado Antonio E. H.⁵⁶⁷⁸⁴^ORCID,Deflon Victor M.⁹¹⁰¹¹⁴^ORCID,Abram Ulrich¹²¹³¹⁴¹⁵^ORCID,Maia Pedro I. S.¹²³⁴^ORCID

Affiliation:

1. Núcleo de Desenvolvimento de Compostos Bioativos (NDCBio)

2. Universidade Federal do Triângulo Mineiro

3. Uberaba

4. Brazil

5. Laboratório de Fotoquímica e Ciência dos Materiais (LAFOT-CM)

6. Instituto de Química

7. Universidade Federal de Uberlândia

8. Uberlândia

9. Instituto de Química de São Carlos

10. Universidade de São Paulo

11. São Carlos

12. Freie Universität Berlin

13. Institute of Chemistry and Biochemistry

14. D-14195 Berlin

15. Germany

Abstract

[PtCl₂(phen)] reacts with β-diketone derived thiosemicarbazones leading to an intramolecular C–C coupling and formation of tetracoordinated N,N,N,S-chelates [Pt^II(phenL^R)].

Funder

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Fundação de Amparo à Pesquisa do Estado de São Paulo

Fundação de Amparo à Pesquisa do Estado de Minas Gerais

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT00367K

Reference26 articles.

1. Understanding and exploiting C–H bond activation

2. Functionalization of Organic Molecules by Transition-Metal-Catalyzed C(sp3)H Activation

3. Reagent-Dependent Formation of C−C and C−F Bonds in Pt Complexes: An Unexpected Twist in the Electrophilic Fluorination Chemistry

4. Unprecedented 1,3-migration of the aryl ligand in metallacyclic aryl α-naphthyl Pt(iv) difluorides to produce β-arylnaphthyl Pt(ii) complexes

5. Carbon−Carbon Bond Formation between Adjacent Alkenyl Ligands: η3-Allyl Iridium(III) and η4-Butadiene Iridium(I) Complexes from a cis-Bis(alkenyl) Iridium(III) Complex

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