Mechanistic insights into polyoxometalate self-assembly in organic solvent: conversion of a cyclic polyoxovanadate-ethoxide to its Lindqvist congener-Reference-Cited by-同舟云学术

Mechanistic insights into polyoxometalate self-assembly in organic solvent: conversion of a cyclic polyoxovanadate-ethoxide to its Lindqvist congener

Published:2020 Issue:61 Volume:56 Page:8607-8610
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Meyer Rachel L.¹²³⁴^ORCID,Love Robert¹²³⁴,Brennessel William W.¹²³⁴^ORCID,Matson Ellen M.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Rochester

3. Rochester

4. USA

Abstract

We report the synthesis of a cyclic hexavanadate polyoxovanadate-alkoxide cluster, [VO(OC2H5)2]6, and its conversion, under solvothermal conditions, to an oxygen-deficient Lindqvist assembly, [V₆O₆(OC₂H₅)₁₂]ⁿ (n = 1−, 0).

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC03464A

Reference31 articles.

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2. Synthesis, structures and applications of electron-rich polyoxometalates

3. Engineering polyoxometalates with emergent properties

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5. Application of time-resolved vanadium-51 2D NMR for quantitation of kinetic exchange pathways between vanadate monomer, dimer, tetramer, and pentamer

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